What Are Dental Resin Materials?
Dec 28, 2024
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Early dental restoration materials were mostly porcelain, alloys, composite materials, etc. Silver-mercury alloy has been used for nearly 150 years and has been banned in some European countries due to its toxicity. The development of dental resin composite materials has advantages such as easy operation. It is composed of resin matrix, etc. People have developed resin matrices with many advantages and optimized the properties by enhancing fillers to meet the needs.
Commonly used resin matrices for dental resins
Epoxy resin matrix
Epoxy resin can show many excellent properties when used as a dental resin matrix, so that patients can have a better experience during use. Epoxy resin is a general term for polymer compounds with two or more epoxy rings in the molecular chain and aliphatic, alicyclic or aromatic as the main chain. Epoxy resin has excellent mechanical properties, strong adhesion, high corrosion resistance, strong plasticity, good electrical insulation and excellent thermal stability, so it is not only widely used in the dental field, but also in many fields such as electronic materials, anti-corrosion coatings and adhesives. In the field of dental applications, epoxy resin is often used for tooth restoration, root canal sealing and orthodontic brackets. As a substitute for traditional alloy materials, epoxy resin has strong operability, better biocompatibility with tooth structure, and elastic coefficient similar to that of teeth. At the same time, epoxy resin is very close to the shape and color of native teeth when repairing teeth.
Methacrylate resin matrix
Resin-based restorative materials are widely used in various direct and indirect repair processes. Generally, the resin matrix is an important component that determines the mechanical properties of the overall material. Resin-based dental materials need to have fluidity or moldability before curing and be able to provide sufficient mechanical strength after curing. Depending on the specific usage characteristics, the resin matrix used is also different. Among them, methacrylate resin is also a commonly used resin matrix. The following are common resin matrices of this type. Bisphenol A glycidyl methacrylate (Bis-GMA) is the earliest resin matrix used in the dental field and is also one of the most common resin matrices. Bis-GMA is composed of bisphenol A (BPA) and glycidyl methacrylate. The steric hindrance of the monomer chain around the benzene ring structure and the presence of hydroxyl groups make Bis-GMA have high viscosity and low hydrophobicity. At the same time, it has a high degree of intermolecular bonding and high bending strength. Bis-GMA has low diffusivity in tissues, which makes it very low in toxicity. However, Bis-GMA has a high viscosity. In order to solve the problem of high viscosity of Bis-GMA, triethanol dimethacrylate (TEGDMA) is usually used with it. Because the interchain polar bond interaction of TEGDMA is weak, the main chain structure is relatively flexible, and the viscosity is low, it is often used as a diluent. Therefore, the two are mixed in different proportions to achieve the required use parameters.

Requirements of dental resin composites
Dental resin composites are used for dental restoration treatment and need to face different oral environments. The restoration will cause stress and deformation to healthy teeth. Therefore, it is necessary to reduce damage to surrounding teeth. This requires that the restoration site is well combined with the original teeth and the material has good plasticity. The load force generated by chewing will cause strain and stress in the restoration, which is related to factors such as the geometry of the material. It is necessary to understand the mechanical strength such as bending strength and modulus in advance, which is usually determined by a three-point bending test to measure whether its performance can be used for dental restoration.
Material application examples




Characteristics of dental resin composites
Dental resin composites are composed of resin matrix and additives. Materials prepared with different components have different lifespans, biocompatibility and water absorption, which affect the restoration effect. To develop new dental materials, it is necessary to optimize the comprehensive performance, prevent physical failure and recurrence of dental caries, evaluate from multiple aspects, and use modification methods to improve mechanical strength, biocompatibility and water absorption.
Dental resin materials replace silver-mercury alloy to repair tooth defects in clinical caries treatment due to their advantages, but the large shrinkage rate of resin polymerization can easily lead to microleakage and increase secondary caries. Endowing dental resin materials with antibacterial properties is one of the important ways to solve this problem. Adding antibacterial agents to dental resin materials is the main method to endow them with antibacterial properties.
Classification of antibacterial agents for dental resin composite
1.Synthetic antibacterial agents: The synthetic antibacterial agents added to dental resins mainly include metals and their oxides, quaternary ammonium salts, and antibiotics. According to the antibacterial performance mode, they are divided into non-release type, release type, and mixed type.
2.Non-release type antibacterial agents: such as quaternary ammonium salt compounds such as methacryloxy dodecylpyridinium bromide, whose antibacterial mechanism is that the negatively charged bacterial cell membrane contacts the positive charge site of the resin, which inactivates the cell enzyme and denatures the protein to kill bacteria. Studies have shown that adhesives containing such antibacterial agents have an anti-caries effect in vivo.
3.Release type antibacterial agents: such as silver nanoparticles, etc., the antibacterial mechanism includes inactivating bacterial cell enzymes and causing oxidative damage. It can inhibit the growth of resin surface and suspended bacteria, but the antibacterial performance disappears after all release, and the short-term release amount is large and cytotoxic.
Mixed antibacterial agents: through the complementary effects of release type and non-release type, the proliferation of free bacteria on the surface of resin materials is inhibited.
As a professional resin 3D material manufacturer, XINSHAN TECH has always taken innovation, focus and achievement as its core values, and has the ability to innovate in 3D printer solutions, CNC processing technology and 3D scanners. XINSHAN TECH has a variety of resin products, such as Dental Resin For 3D Printing, Resin 3d Printed Jewelry, etc., which have been used in many dental fields.
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